The Instituto de Ciencia de Materiales de Madrid (ICMM) is an institute of the Consejo Superior de Investigaciones Cientificas (CSIC) (Spanish National Research Council) founded in December 1986, that belongs to the Area of Science and Technology of Materials, one of the eight Areas in which the CSIC divides its research activities.


Our mission is to create new fundamental and applied knowledge in materials of high technological impact, their processing and their transfer to the productive sectors at local, national and European scales (the true value of materials is in their use), the training of new professionals, and the dissemination of the scientific knowledge.

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Forthcoming Events


Thermally driven out-of-equilibrium two-impurity Kondo system

Rosa López  read more


La litografía de oxidación local para la fabricación de dispositivos nanoelectrónicos
Francisco Miguel Espinosa Barea  read more


Topological defect engineering in ferroelectrics: from domain wall memory to emergent functionalities
Prof. Nagarajan VALANOOR  read more

Large birefringence and linear dichroism in TiS3 nanosheets

Nikos Papadopoulos, Riccardo Frisenda, Robert Biele, Eduardo Flores, Jose R. Ares,de Carlos Sánchez, Herre S. J. van der Zant, Isabel J. Ferrer, Roberto D'Agosta and Andres Castellanos-Gomez

TiS3 nanosheets have proven to be promising candidates for ultrathin optoelectronic devices due to their direct narrow band-gap and the strong light–matter interaction. In addition, the marked in-plane anisotropy of TiS3is appealing for the fabrication of polarization sensitive optoelectronic devices. Herein, we study the optical contrast of TiS3 nanosheets of variable thickness on SiO2/Si substrates, from which we obtain the complex refractive index in the visible spectrum. We find that TiS3 exhibits very large birefringence, larger than that of well-known strong birefringent materials like TiO2 or calcite, and linear dichroism. These findings are in qualitative agreement with ab initio calculations that suggest an excitonic origin for the birefringence and linear dichroism of the material.

Nanoscale, 2018

Mapping the color of TiS3 flakes to their thickness. (a) Optical image of an exfoliated thin flake of TiS3 on 90 nm SiO2/Si substrate. (b) AFM topography of the same flake from panel (a). The thickness of the particular flake is 4.2 nm. (c–j) Optical images of flakes with different thickness and a colorbar with the colors of flakes with thickness up to 110 nm. The scale bars are 5 μm.

ICMM-2018 - Sor Juana Inés de la Cruz, 3, Cantoblanco, 28049 Madrid, Spain. Tel: +34 91 334 9000. info@icmm.csic.es